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What is the difference between distilled and deionized water? Can I use deionized water in my boiler? Do not use deionized water in your boiler! Use only distilled water in your small-scale steam boiler. Your engine will run on deionized water or even ordinary tap water. But there are problems with each of these which we should avoid.
Tap water contains minerals which will stay behind when you boil the water out of the boiler. When you run your steam engine, you are in essence distilling the water in the boiler. What comes out the regulator is pure water vapor, and the minerals are left behind in your boiler as scale. When you use distilled water in the boiler, there is nothing left when you're finished.
Scale reduces the boiler's ability to transfer heat to the water, and thus reduces the efficiency of your engine. Eventually, the lines may become so clogged with scale that you can't get any steam out of the boiler at all. Operators of larger engines can sometimes remove the scale physically by scraping or brushing. We have no such small scrapers and brushes, though. Scale can sometimes be removed by boiling vinegar or some other very weak acid in the boiler. This should not be considered a desirable alternative to using distilled water, however. Stick with distilled water and you won't have to worry about mineral scale.
Deionized water contains no ions, which means it has had the chemically reactive molecules removed. If put into contact with metals, however, it will happily take on new ions, with disastrous results. Mike Chaney wrote about the effect of using deionized water at a UK exhibition:
After about a weeks running some of the loco boilers started to "weep", although they had been properly tested and certified. An investigation showed that the silver soldered joints were failing because the water was trying to grab back ions from any metal with which it came into contact. Copper, zinc and silver were found to be particularly susceptible.
Moral: for the long-term health of your boiler, avoid deionized water!
Bob Stiegler wrote
I bought two measuring devices at the local wholesale nursery supply co. One measures pH, the other total water hardness. I tried them out on collected rainwater, and measured 7.5 pH (neutral) and approx 5 ppm total hardness (verrrrrry soft). Not having the facilities for collecting large amounts of rainwater (and having no way to collect any rainwater whatsoever when its snowing), I bought some bottled water. It was also neutral and sufficiently soft, but expensive. I then saw something called an RO (reverse osmosis) watermaker in a tropical fish supply catalog. Not cheap ($200.00, approx), but very effective (7.5 pH, 1 ppm total hardness). It takes a couple of hours to fill a 7.5 gallon water bottle. My plants thrived, and I didn't go bankrupt buying soft neutral water.
While this is a bit too expensive to be justified by the the average small-scale live steamer, it's something which could be attractive for a club to buy as a group. Or, if you keep tropical plants or fish, you might well get enough use of it to justify one yourself.