Most chergers won't discharge a battery completely, I use a 12V taillight bulb wired to a suitable connector and plug this in to a part discharged pack. (1 to 4S) . When no light is visible the battery is near totally discharged, complete discharge can be done by then shorting the cells, the voltage is so low that this is safe to do this.Alternatively leave the pack in a container of salt water, this does take longer. The cells can then be disposed of, I generally take 1 more step by slitting the cells in a container of water and leave them for a few days, this will destroy any unreacted lithium in the cell, they can then be disposed of with normal household waste. (make sure the cells are fully discharged using the bulb before doing this)For larger packs I have a connector with crocodile clips for the bulb, I open up the end of the pack to expose the connections and treat it as 2 packs for dischargeing.
Jim