The reason for the bar-litre rule is that it is the VOLUME of stored water at 100 deg.C + is the real hazard- you could store 50ml of water at 500 deg. C @ 300psi and have it explode and it would do far less damage than 100L of water stored at 180 deg. C @ 120psi-
Steam expands at 1600 X it's volume under pressure at a rate appertaining to it's stored energy potential (latent heat)
Water stored at above 100 deg. C under pressure will flash into steam under conditions of any pressures and temperatures less than it is stored at- this rate is again controlled by it's stored potential
On the stroed LPG side-
LPG- specifically 70/30 Butane/Propane mix- has an explosive window of between 2% Gas to air and 9% Gas to air ratio, below that and it will 'flash' or 'pop' off, above that and it will catch fire making a smoky yellow flame.
Like water in a boiler it will flash into an explosive gas when subjected to atmospheric pressures and temperatures above it's boiling point (due to the rapid temperature increase this time, as opposed to rapid temperature change in the case of steam).
Usually this event would be caused by a rupture in the gas tank (EXTREMELY rare, I have never heard of it happen, I don't know about anyone else on here?)
A rupture in a supply pipe would vent the gas, and is potentially explosive- but the conatainer it fills- the boat hull- being usually very small in volume compared to the volume of evaporated stored LPG in the tank itself would pose a very real, however fairly low-risk, explosion hazard.
Greg